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Tile Guard Heavy Duty Acidic Cleaner-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Tile cleanrStructure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 2024One PPG Place
Pittsburgh PA 15272
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 000111-76-2 -- 1.0-5.0 Xn, Xi -- -- -- -- 009036-19-5 -- 1.0-5.0 -- -- -- -- 007664-38-2 -- 10.0-20.0 C, Xi -- -- -- -- 007647-01-0 -- 10.0-20.0 T, C -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)2-Butoxyethanol
000111-76-2
203-905-01.0-5.0 No H302, H315, H319 P264, P270, P280, P301+P312, P302+P352, P305+P351+P338, P330, P332+P313, P337+P313, P362+P364, P501 No No Octylphenoxypoly(ethoxyethanol)
009036-19-5
--1.0-5.0 No -- -- -- Yes H Phosphoric acid
007664-38-2
231-633-210.0-20.0 No H290, H302, H314 P234, P390, P406, P260, P264, P270, P280, P301+P312, P301+P330+P331, P303+P361+P353, P330, P363, P304+P340, P310, P321, P305+P351+P338, P405, P501 No No Hydrochloric acid
007647-01-0
231-595-710.0-20.0 No H331, H314 P101, P261, P280, P305+P351+P338, P314, P403+P233, P405 No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H290 : May be corrosive to metalsH302 : Harmful if swallowedH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH319 : Causes serious eye irritationH331 : Toxic if inhaled
- P101 : If medical advice is needed, have product container or label at handP234 : Keep only in original containerP260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP270 : Do not eat, drink or smoke when using this productP280 : Wear protective gloves/protective clothing/eye protection/face protectionP310 : Immediately call a POISON CENTER or doctor/physicianP314 : Get Medical advice/attention if you feel unwellP321 : Specific treatment (see … on this label)P330 : Rinse mouthP363 : Wash contaminated clothing before reuseP390 : Absorb spillage to prevent material-damageP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP301+P330+P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomitingP302+P352 : IF ON SKIN: Wash with soap and waterP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP332+P313 : If skin irritation occurs: Get medical advice/attentionP337+P313 : Get medical advice/attentionP405 : Store locked upP406 : Store in a corrosive resistant/… container with a resistant inner linerP501 : Dispose of contents/container to
- GHS04 : Compressed GasGHS05 : CorrosiveGHS06 : ToxicGHS07 : Irritant
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :October 02, 2007 Date when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
MSDS Verified :December 28, 2009 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
DANGER POISON. KEEP OUT OF REACH OF CHILDREN. CAUTION: Contains HYDROCHLORIC ACID, PHOSPHORIC AND 2-BUTOXYETHANOL. POISON: Fatal if swallowed. CORROSIVE: Causes severe burns. Vapor Harmful. Use only with adequate ventilation. Avoid breathing vapors, sprays or mists. Do not swallow or take internally. Do not get in eyes, on skin or on clothing. Wash thoroughly after handling. Keep container closed. Use only in a well-ventilated area.
Keep away from heat, sparks and flame. Do not expose to heat or store at temperatures above 120 deg. F. Open container carefully. Clean up spills, rags and papers, and dispose of them promptly. -
Acute health effects
From MSDS:
Hazards Idenrification
Potential Health Effects
Eye: Corrosive. Vapors are irritating and may cause damage to the eyes. Contact may cause severe burns and permanent eye damage.
Skin: Corrosive! Can cause redness, pain, and severe skin burns.
Ingestion: POISON: MAY BE FATAL IF SWALLOWED. CORROSIVE! Can cause immediate pain and burns of the mouth, throat, esophagus and gastrointestinal tract. May cause nausea, vomiting, and diarrhea, and in severe cases, death.
Inhalation: Corrosive! Inhalation of vapors can cause coughing, choking, inflammation of the nose, throat, and upper respiratory tract, and in severe cases, can lead to chemical pneumonitis and pulmonary edema.
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Chronic health effects
From MSDS:
Long term exposure to concentrated vapors may cause erosion of teeth. Long term exposures seldom occur due to corrosive properties of the acid. -
Carcinogenicity
NTP: No
IARC: Group 3 -
Handling information
POISON: MAY BE FATAL IF SWALLOWED. DANGER: Contains Hydrochloric Acid and Phosphoric Acid. CORROSIVE: Causes severe burns. Do not get in eyes, on skin or clothing. VAPORS HARMFUL: Do not breathe or swallow vapor or fumes. Fumes are corrosive to metal. Do not use chlorine bleach, mildew removers, or any other products, as toxic fumes may result.
Store securely closed in original container in a well ventilated area inaccessible to small children or pets. Do not reuse empty container. When empty, rinse thoroughly with water and recycle container or discard in the trash. Keep Out Of Reach Of Children. -
Disposal information
Follow federal, provincial or state and local government requirements for disposal. Container disposal: Do not reuse empty container. Carefully rinse empty container and wrap in newspaper then discard in trash or rinse and recycle if appropriate.
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California Prop. 65 Warning
Not listed.
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First Aid
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Skin: Immediately flush skin with plenty of water for at least 15 minutes. Remove any contaminated clothing and wash thoroughly before reuse.
Eye: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Ingestion: DO NOT INDUCE VOMITING. Give large quantities of water and get medical attention immediately. Never give anything by mouth to an unconscious person.
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